Highly Selective Olefin-Assisted PdII -Catalyzed Oxidative Alkynylation of Enallenes
نویسندگان
چکیده
منابع مشابه
Highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc02660e
A highly selective olefin-assisted palladium-catalyzed oxidative carbocyclization via remote olefin insertion to afford cyclohexenes has been developed. It was shown that the assisting olefin moiety was indispensable for the formation of the cyclohexene product. Furthermore, preliminary studies on chiral anion-induced asymmetrical carbocyclization-borylation of enallenes have been carried out.
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ژورنال
عنوان ژورنال: Chemistry - A European Journal
سال: 2017
ISSN: 0947-6539
DOI: 10.1002/chem.201701654